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How lightning is produced by convective storms is rather poorly understood. It exists because of large potential differences between regions of positive and negative charge (between the ground and clouds or from one portion of cloud to another). Current research indicates that lightning is favored by a mixture of ice crystals and subcooled liquid drops (not frozen) within a strong updraft. Lightning bolts primarily transfer a negative charge from cloud to ground but can transfer positive charge. Though most lightning flashes appear to last only a fraction of a second, many strikes are actually a series of shorter duration bolts (of which there could be 5 to 25 or more). This is the reason I have so many daytime lightning photos. The thunder we hear is generated by the sudden expansion and contraction of air that is heated by the lightning bolt.
One of the safest places of all (besides underground) is a car. A car is not safe because it has rubber tires (what a horrible myth); it is safe because the electrical current quickly disperses around the body of the car and into the ground very effectively (acts as a Faraday cage). A house is also quite safe but lightning has penetrated windows or traversed plumbing or electrical wires and killed people. That's why you are often told to stay off the phone and avoid showers or baths during electrical storms. If caught in the open, you should not seek cover under a tree especially lone trees in otherwise open areas. Instead your best safety measure is to crouch down (don't lie) as close to the ground as possible - hug your knees. Forget the other myth about rubber sneakers, they won't protect you in the least. This only scratches the surface of lightning safety - for more details, I highly recommend the Lightning Safety Institute website.
Photographing lightning at night is relatively easy provided you have access to remote areas away from town/city lights. One cardinal rule to obey: always focus at infinity. Anything less is plain stupidity. Associated with this rule: disable auto-focus, manually focus to infinity and do not touch it again. Here are some tips to help you:
Additional general photography tips and advice.
Book: Colorado Weather Almanac by Mike Nelson
Web: Lightning Safety Institute